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Aluminium oxide

 

Aluminium oxide

Properties
General
Name Aluminium oxide
Aluminum oxide (US)
Chemical Formula Al2O3
Appearance White crystalline powder or solid

Physical

Formula weight 101.96 amu
Melting point at SP 2303 K
Boiling point at SP 3250 K
Density 3.97 × 103 kg/m3
Crystal structure Trigonal (hex)
Solubility Insoluble

Thermochemistry

ΔfH0liquid −1620.57 kJ/mol
ΔfH0solid −1675.69 kJ/mol
S0liquid, 1 bar 67.24 J/mol·K
S0solid 50.9 J/mol·K

Safety

Ingestion Low hazard
Inhalation May cause irritation or lung damage
Skin Low hazard
Eyes Low hazard
SI units were used where possible.
Aluminium oxide or aluminum oxide is a chemical compound of aluminium and oxygen with chemical formula . It is also commonly referred to as alumina in the mining, ceramic, and materials science communities. Aluminium oxide is the main component of bauxite, the principal ore of aluminium. Industrially, bauxite is purified to aluminium oxide via the Bayer process, and then converted to aluminium metal in the Hall-Heroult process.

The gems ruby and sapphire are mostly aluminium oxide, given their characteristic colors by trace impurities.

Aluminium oxide is responsible for metallic aluminium's resistance to weathering. Metallic aluminium is very reactive with atmospheric oxygen, and a thin layer of aluminium oxide quickly forms on any exposed aluminium surface. This layer protects the metal from further oxidation. The thickness and properties of this oxide layer can be enhanced using a process called anodising.

Aluminium oxide is an excellent thermal and electrical insulator. In its crystalline form, called corundum, its hardness makes it suitable for use as an abrasive and as a component in cutting tools.

Powdered aluminium oxide is frequently used as a medium for chromatography.

In August, 2004, scientists in the United States working for 3M developed a technique for making an alloy of alumina and rare earth elements to produce a strong glass called transparent alumina.

Aluminium oxide was taken off the EPA's chemicals lists in 1988.

External links

  • PhysicsWeb article on Transparent alumina



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